- Fat connectivity proxy
- 0.0395
- Cocoa particle crowding
- 0.612
- Free water fraction
- 23.7%
- Aqueous viscosity
- 11.78 mPa·s
- Fat blend evidence
- extrapolated
- Process interpretation
- reference-window
Warnings
- Glucose DE estimates number-average molecular weight; equal-DE syrups can still differ in saccharide distribution and functionality.
- CB/milk-fat eutectic estimate is outside the strongest 10-25 C, 0-30% milk-fat reference domain.
- Published and industrial fat-blend references disagree materially; the SFC interval is intentionally wide.
- GFI range is widened because cocoa-butter/milk-fat SFC references disagree for this blend region.
- Cocoa-particle volume uses a fixed density and does not yet model fibre swelling or particle-size distribution.
- Dissolved-solids volume is a structural proxy; concentrated sugar/polyol solutions have non-additive volumes.
- v0.5 separates cocoa-fibre crowding from fat connectivity: cocoa can reinforce the matrix while also hindering partial coalescence.
- Trehalose, lactose, sorbitol and glucose-syrup solids currently use sucrose-like viscosity weighting while retaining their own molecular behavior elsewhere; this is an explicit mixture extrapolation.
- Milk proteins/minerals and unspecified soluble solids are excluded from the carbohydrate-viscosity fit; predicted aqueous viscosity is therefore a carbohydrate-phase estimate, not full serum rheology.
Sources
McGill & Hartel, Journal of Food Science (2018)published-dataDirect ganache evidence: crystalline fat content and insoluble cocoa particle loading increase firmness; soluble sugar and milk solids soften the system.
DOI 10.1111/1750-3841.14053 Castro-Alayo et al., Foods (2022)published-modelPure cocoa-butter Avrami kinetics at 15-19 C. We reconstruct k from published n and theoretical half-time because the published 19 C row contains an internal n/k/t1/2 inconsistency.
DOI 10.3390/foods11121769 Rong, Sillick & Gregson, Journal of Food Science (2009)published-modelTheoretical DE relation DE = Mglucose/Mn * 100 is used to estimate number-average molecular weight for colligative calculations.
DOI 10.1111/j.1750-3841.2008.00993.x Representative cocoa-butter p-NMR SFC datapublished-dataGeneric SFC curve; botanical origin, polymorph and thermal history remain product-specific.
Representative anhydrous milk-fat SFC datapublished-dataMilk-fat SFC varies substantially with season and region; this curve is a central estimate.
Confectionery gelatin in concentrated sugar solutionsextrapolatedAnchors gelatin thermal trends, but Namelaka gelatin concentrations are much lower than the 4-6% systems studied.
DOI 10.1016/j.foodhyd.2021.107132 Ganache secondary network agingcalibrationHours-scale organization after primary fat crystallization; intentionally separate from published primary Avrami kinetics.
GFI perceptual mappingcalibrationLogistic mapping from latent structure to 0-100; not a physical law.